You can't export a file from Civil 3D to Solibri because Solibri doesn't have support for it. According to Autodesk information, the Solibri application is compatible with the following products. Autodesk AutoCAD Architecture Version: 2015, 2014, 2013 Autodesk AutoCAD MEP Version: 2015, 2014, 2013 Autodesk Revit Version: 2015, 2014, 2013 Autodesk Revit Architecture Version: 2015, 2014, 2013 Autodesk Revit MEP Version: 2015, 2014, 2013 Autodesk Revit Structure Version: 2015, 2014, 2013 However, there is a way to export to IFC from Civil 3D.

There is an ample discussion at the Autodesk forums: http://forums.autodesk.com/t5/autocad-civil-3d-general/civils-3d-to-ifc/td-p/4589219.

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